Gerhard Franz (Munich University of Applied Sciences, Germany); Ralf Meyer, Markus-Christian Amann (Technische Universität München, Germany)
Reactive ion etching is the interaction of reactive plasmas with surfaces. For a detailed understanding, significant properties of reactive composite low pressure plasmas driven by electron cyclotron resonance were investigated and compared with the radial uniformity of the etch rate. The determination of electronic properties of chlorine and hydrogen containing plasmas enabled the understanding of the pressure dependent resonance behavior and gave a better insight into the electronic parameters of reactive etch gases. With electrical evaluation of I(V) characteristics obtained with a Langmuir probe, differently composed plasmas were investigated and the most important methods of analyzing the I(V) characteristics were compared. A mathematical model to reduce noise sensitivity was used and compared to the standard method of Druyvesteyn to derive the electron energy distribution functions. Special attention was payed to the power of the energy dependence in the exponent. Especially for plasmas which are generated by electron cyclotron resonance with EM modes, the existence of Maxwellian distribution functions are not to be taken as a self-evident fact, but it was proven for Ar- and Kr-stabilized plasmas. Aside from the electron temperature, which could be derived within a certainty of ten percent using the discussed methods, the global uniform discharge model of Lieberman has been shown to be useful to calculate the neutral gas temperature. To what extent the invasive method of using a Langmuir probe could be replaced with the non-invasive optical method of emission spectroscopy, especially actinometry, was investigated and the resulting data showed the same relative behavior as Langmuir data.
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